Effect of feed composition on methanol conversion to light olefins over SAPO-34

• Published in: Applied catalysis. A, General Vol. 218; no. 1; pp. 241 - 250
• Main Authors: Wu, Xianchun, Anthony, R.G.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 25.09.2001; Elsevier
• Subjects: Catalysis; Catalytic reactions; Chemistry; Ethene; Exact sciences and technology; General and physical chemistry; Methanol; Olefins; Propene; SAPO-34; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Zeolite; Ethene; Propene; Zeolite; SAPO-34; Olefins; Methanol; Water; Catalytic reaction; Hydrocarbon; Acidic site; Ethylene; Composition effect; Selectivity; Experimental study; Molecular sieve; Primary alcohol; Heterogeneous catalysis; Aqueous solution; Butene; Ethylenic compound
• ISSN: 0926-860X; 1873-3875
• DOI: 10.1016/S0926-860X(01)00651-2

Effects of adding ethene, propene, and water to methanol feed on conversion of methanol to olefins are investigated over SAPO-34 catalyst. When ethene is fed to the reactor along with methanol and water, selectivity to ethene decreases, but the selectivity to propene and butenes increases. When propene is fed with methanol and water, the selectivity to propene decreases but increases to ethene and butenes. An analysis of the results indicates that ethene and propene react with methanol over SAPO-34 to form propene and butenes, respectively. These reactions need stronger acidic sites than the conversion of methanol to olefins. The presence of propene in the feed inhibits the reaction of ethene with methanol through competition for the stronger acidic sites. The addition of water to the feed with methanol results in the reduction of the rate of coke formation and aids in maximizing the selectivity to olefins. The optimum water content in the feed appears to be 73–80 mol%. At this concentration, the catalyst can process more than eight times the amount of methanol than when feeding pure methanol prior to a decrease in the methanol conversion <100%.