Fluorescence sensing and device fabrication with luminescent metal-organic frameworks

Metal-organic frameworks (MOFs) are a novel class of hybrid porous multi-functional materials consisting of metal ions/clusters and organic ligands. MOFs have exclusive benefits due to their tunable structure and diverse properties. Luminescent MOFs (LMOFs) exhibit both porosity and light emission....

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 53; no. 2; pp. 394 - 49
Main Authors Cai, Ding-Gui, Zheng, Teng-Fei, Liu, Sui-Jun, Wen, He-Rui
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 02.01.2024
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Summary:Metal-organic frameworks (MOFs) are a novel class of hybrid porous multi-functional materials consisting of metal ions/clusters and organic ligands. MOFs have exclusive benefits due to their tunable structure and diverse properties. Luminescent MOFs (LMOFs) exhibit both porosity and light emission. They display abundant host and guest responses, making them conducive to sensing. Currently, LMOF sensing research is gaining more depth, with attention given to their device and practical applications. This work reviews recent advancements and device applications of LMOFs as chemical sensors toward ions, volatile organic compounds, biomolecules, and environmental toxins. Furthermore, the detection mechanism and the correlation between material properties and structure are elaborated. This analysis serves as a valuable reference for the preparation and efficient application of targeted LMOFs. Recent progress in luminescent metal-organic frameworks for detecting ions, volatile organic compounds, biomolecules and environmental toxins and device fabrication has been reviewed.
Bibliography:Teng-Fei Zheng obtained her BS from Nanchang University in 2008, her MS in the group of Prof. Chao Chen from Nanchang University in 2011, and her PhD from Jiangxi University of Science and Technology in 2020 under the supervision of Prof. He-Rui Wen. Her research focuses on functional coordination complexes including molecular magnetorefrigerant materials and functional metal-organic frameworks.
Sui-Jun Liu obtained his BS from Nanchang University in 2009 and his PhD from Nankai University in 2014 under the supervision of Prof. Xian-He Bu. Then, he joined Jiangxi University of Science and Technology and became an associate professor at the same university in 2017. From 2017 to 2018, he was a visiting scholar at the Texas A&M University in Prof. Kim Dunbar's group. He is now the associate dean of the School of Chemistry and Chemical Engineering at Jiangxi University of Science and Technology. His research interest is focused on functional metal-organic frameworks and molecular magnetic materials.
He-Rui Wen obtained his PhD in inorganic chemistry in 2006 from Nanjing University under the supervision of Prof. Xiao-Zeng You. From 1984, he worked at the Department of Chemistry, Gannan Normal University and he became a professor in 2000. In 2008, he moved to Jiangxi University of Science and Technology. He is now a professor of inorganic chemistry, and the president of Jiangxi University of Science and Technology. His research focuses on molecule-based magnetic materials and multifunctional molecular materials.
Ding-Gui Cai obtained her BS from Jiangxi University of Science and Technology in 2021. She is now in the master's degree program of the School of Chemistry and Chemical Engineering at Jiangxi University of Science and Technology under the guidance of Dr Sui-Jun Liu. Her research focuses on the design and synthesis of luminescent metal-organic frameworks with chemical sensing.
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ISSN:1477-9226
1477-9234
1477-9234
DOI:10.1039/d3dt03223j