Indium-catalyzed inter- and intramolecular dithianyl-alkyne metathesis reactions
Herein, we reported an efficient indium catalyzed dithianyl-alkyne metathesis ( DAM ) reaction. This strategy allows for the formation of a new C-C double bond and valuable C-S bonds during the metathesis event, and was successfully applied to the synthesis of diverse vinyl dithianyl substituted org...
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Published in | Chemical communications (Cambridge, England) Vol. 6; no. 1; pp. 1285 - 1288 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
CAMBRIDGE
Royal Soc Chemistry
30.01.2024
Royal Society of Chemistry |
Subjects | |
Online Access | Get full text |
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Summary: | Herein, we reported an efficient indium catalyzed dithianyl-alkyne metathesis (
DAM
) reaction. This strategy allows for the formation of a new C-C double bond and valuable C-S bonds during the metathesis event, and was successfully applied to the synthesis of diverse vinyl dithianyl substituted organic molecules.
Development of a novel indium-catalyzed inter- and intramolecular dithianyl-alkyne metathesis with high atom economy and wide functional group tolerance, giving a broad range of 1,3-dithianyl substituted unsaturated compounds under mild conditions. |
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Bibliography: | Electronic supplementary information (ESI) available. CCDC For ESI and crystallographic data in CIF or other electronic format see DOI https://doi.org/10.1039/d3cc05622h 2308103 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/d3cc05622h |