Indium-catalyzed inter- and intramolecular dithianyl-alkyne metathesis reactions

Herein, we reported an efficient indium catalyzed dithianyl-alkyne metathesis ( DAM ) reaction. This strategy allows for the formation of a new C-C double bond and valuable C-S bonds during the metathesis event, and was successfully applied to the synthesis of diverse vinyl dithianyl substituted org...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 6; no. 1; pp. 1285 - 1288
Main Authors Chen, Xi, Li, Rui-peng, Long, Peng, Tang, Yuxi, Li, Jia, Tang, Shouchu
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 30.01.2024
Royal Society of Chemistry
Subjects
Alkynes
Chemistry
Chemistry, Multidisciplinary
Indium
Metathesis
Organic chemistry
Physical Sciences
Science & Technology
CARBONYL METATHESIS
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Summary:Herein, we reported an efficient indium catalyzed dithianyl-alkyne metathesis ( DAM ) reaction. This strategy allows for the formation of a new C-C double bond and valuable C-S bonds during the metathesis event, and was successfully applied to the synthesis of diverse vinyl dithianyl substituted organic molecules. Development of a novel indium-catalyzed inter- and intramolecular dithianyl-alkyne metathesis with high atom economy and wide functional group tolerance, giving a broad range of 1,3-dithianyl substituted unsaturated compounds under mild conditions.
Bibliography:Electronic supplementary information (ESI) available. CCDC
For ESI and crystallographic data in CIF or other electronic format see DOI
https://doi.org/10.1039/d3cc05622h
2308103
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc05622h