The solvent and zinc source dual-induced synthesis of a two dimensional zeolitic imidazolate framework with a farfalle-shape and its crystal transformation to zeolitic imidazolate framework-8

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 49; no. 8; pp. 2437 - 2443
• Main Authors: Jin, Chun-Xin, Wang, Yu, Gao, Qiu-Shan, Yao, Dan-Yang, Wang, Si-Hong, Li, Donghao, Shang, Hai-Bo
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 25.02.2020
• Subjects: Adsorption; Metal-organic frameworks; Performance enhancement; Pore size; Porosity; Recrystallization; Room temperature; Solvents; Structural hierarchy; Synthesis; Topology; Zeolites; Zinc acetate
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/c9dt04747f

Exploring new zeolitic imidazolate frameworks (ZIFs) with specific topologies and pore structures is important for extending applications and improving performances. In this work, a new farfalle-shaped ZIF with an ordered hierarchical structure (named ZIF-F) was easily built with zinc acetate and 2-methylimidazole (MeIm) in an aqueous system at room temperature. The synthesis mechanism of ZIF-F is a dual-induction interaction of a solvent and zinc source based on the synthesis protocol of ZIF-8. The prepared ZIF-F is a 3-5 μm dispersible particle constructed from numerous nanoplates with the same building units as ZIF-8. ZIF-F has a rich 4 nm inter-particle spacing with a 0.1074 cm 3 g −1 total pore volume and exhibits high thermo- and solvent stability. It is worth noting that crystal transformation could occur from ZIF-F to ZIF-8 in methanol via the dissolution-recrystallization route. Regarding the adsorption of Congo red (CR), ZIF-F exhibits better adsorption capacity (182.82 mg g −1 ) than ZIF-8 (149.25 mg g −1 ) with 6 times higher adsorption rate than that of ZIF-8 because of the positive effect of its larger pore size and hierarchical structure. A new 2D ZIF with a farfalle-shape was easily built with zinc acetate and 2-methylimidazole in an aqueous system at room temperature.