Formation of an Unusual Product in the Reaction of a 1,2,5-Thiadiazolidine 1,1-Dioxide-Derived Thioether with Sulfuryl Chloride

The treatment of a 1,2,5-thiadiazolidine 1,1-dioxide-derived phenylthiomethyl ether with sulfuryl chloride yielded an unexpected dimeric product whose structure was determined using X-ray crystallography. A plausible mechanism for the formation of this product is proposed.

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Bibliographic Details
Published inJournal of heterocyclic chemistry Vol. 46; no. 4; pp. 669 - 673
Main Authors Dou, Dengfeng, Talaty, Erach R., Moore, Curtis E., Bullinger, John C., Eichhorn, David M., Groutas, William C.
Format Journal Article
LanguageEnglish
Published HOBOKEN Wiley 01.07.2009
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
PATHOGENESIS
APOPTOSIS
OBSTRUCTIVE PULMONARY-DISEASE
DESIGN
MECHANISM
INHIBITORS
COPD
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Summary:The treatment of a 1,2,5-thiadiazolidine 1,1-dioxide-derived phenylthiomethyl ether with sulfuryl chloride yielded an unexpected dimeric product whose structure was determined using X-ray crystallography. A plausible mechanism for the formation of this product is proposed.
ISSN:0022-152X
1943-5193
DOI:10.1002/jhet.136