Triphenylphosphine catalyzed formation of functionalized 2-aminothiophenes

Triphenylphosphine was used as a nucleophilic catalyst in the addition–cyclization reaction of phenyl isothiocyanate with electron‐deficient allenes. This strategy offers a new approach for the synthesis of 2‐aminothiophenes under neutral conditions. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18...

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Published inHeteroatom chemistry Vol. 18; no. 3; pp. 312 - 315
Main Authors Virieux, David, Guillouzic, Anne-Françoise, Cristau, Henri-Jean
Format Journal Article
LanguageEnglish
Published Hoboken Wiley Subscription Services, Inc., A Wiley Company 01.04.2007
Wiley
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Summary:Triphenylphosphine was used as a nucleophilic catalyst in the addition–cyclization reaction of phenyl isothiocyanate with electron‐deficient allenes. This strategy offers a new approach for the synthesis of 2‐aminothiophenes under neutral conditions. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:312–315, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20300
Bibliography:ArticleID:HC20300
istex:5BA76BC920880C4C1974EF302A65396DE94C2A1A
ark:/67375/WNG-2XQFJ3BL-N
ISSN:1042-7163
1098-1071
DOI:10.1002/hc.20300