A composite counter electrode of CoS/MWCNT with high electrocatalytic activity for dye-sensitized solar cells

• Published in: Electrochemistry communications Vol. 13; no. 9; pp. 977 - 980
• Main Authors: Lin, Jeng-Yu, Liao, Jen-Hung, Hung, Tzu-Yu
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 01.09.2011; Amsterdam Elsevier; New York, NY
• Subjects: Applied sciences; CoS; Counter electrode; Dye-sensitized solar cell; Electrocatalytic activity; Energy; Exact sciences and technology; MWCNT; Natural energy; Photovoltaic conversion; Solar cells. Photoelectrochemical cells; Solar energy; Dye-sensitized solar cell; MWCNT; Electrocatalytic activity; CoS; Counter electrode; Scanning electron microscopy; Fluorine; Cobalt Sulfides; Doped materials; Carbon nanotubes; Composite material; Surface structure; Electrocatalysis; Energy-dispersive X-ray spectrometry; Counterelectrode; Multiwalled nanotube; Morphology; Tin Oxides; Photovoltaic conversion
• ISSN: 1388-2481; 1873-1902
• DOI: 10.1016/j.elecom.2011.06.016

In this study, CoS coated multi-wall carbon nanotube (CoS/MWCNT) counter electrode (CE) was first incorporated into Pt-free dye-sensitized solar cell (DSSC). This composite film was fabricated using an electrophoresis of MWCNTs onto a fluorinated tin oxide (FTO) substrate and then subjected to CoS electrodeposition. The cyclic voltammetric tests recorded an enhanced electrocatalytic activity when the CoS was deposited onto the surface of the MWCNTs. Additionally, consecutive cyclic voltammetric tests demonstrated that the CE possessed excellent electrochemical stability. Thus, the DSSC assembled with CoS/MWCNT CE showed an enhanced photovoltaic conversion efficiency of 6.96% (compared to 2.91% for DSSCs with MWCNT CE or 5.86% for CoS CE alone) under full sunlight illumination (100 mW cm − 2 , AM 1.5 G) due to the superior electrocatalytic activity of the out-shell CoS material and highly specific surface of the MWCNTs. Therefore, the CoS/MWCNT composite can be considered as a promising alternative CE for use in low-cost DSSCs. ► CoS/MWCNT composite electrodes were first incorporated in Pt-free DSSCs. ► An enhanced electrocatalytic activity of CoS/MWCNT electrode was demonstrated. ► The DSSC with the CoS/MWCNT CE showed an enhanced cell efficiency of 6.96%.