Improved procedure for the preparation of diethyl ketone triperoxide and kinetics of its thermal decomposition reaction in solution

Diethyl ketone triperoxide is obtained in a simple and efficient one-step procedure using the acid-catalysed oxidation reaction of diethyl ketone by hydrogen peroxide. Its thermolysis in toluene solution is initiated by a rate determining peroxidic bond rupture of that substituted triperoxane molecu...

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Bibliographic Details
Published inTetrahedron letters Vol. 34; no. 11; pp. 1745 - 1746
Main Authors Eyler, G.N., Cañizo, A.I., Alvarez, E.E., Cafferata, L.F.R.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 12.03.1993
Elsevier
Subjects
Chemistry
Chemistry, Organic
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Organic chemistry
Physical Sciences
Preparations and properties
Science & Technology
Nine membered ring
Toluene
Oxidation
Acid catalysis
Oxygen heterocycle
Ketone
Hydrogen Peroxides
Organic peroxide
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Summary:Diethyl ketone triperoxide is obtained in a simple and efficient one-step procedure using the acid-catalysed oxidation reaction of diethyl ketone by hydrogen peroxide. Its thermolysis in toluene solution is initiated by a rate determining peroxidic bond rupture of that substituted triperoxane molecule. Diethyl ketone triperoxide is obtained in one-step procedure using acid-catalysed oxidation reaction of diethyl ketone by hydrogen peroxide. Its thermolysis in toluene is initiated by a rate determining peroxidic bond rupture of the molecule.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(00)60767-0