Synthesis of optically active furfuryl alcohols and butenolides from trans-1-trimethylsilyl-3-alken-1-ynes via successive asymmetric dihydroxylation and hydromagnesiation reactions

Optically active furfuryl alcohols and hydroxy butenolides are prepared from trans-1-trimethylsilyl-3-alken-1-ynes by the successive asymmetric dihydroxylation and hydromagnesiation reactions. Graphic

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Bibliographic Details
Published inTetrahedron letters Vol. 34; no. 31; pp. 4975 - 4978
Main Authors Tani, Kousuke, Sato, Yoshitaka, Okamoto, Sentaro, Sato, Fumie
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 30.07.1993
Elsevier
Subjects
Chemistry
Chemistry, Organic
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Organic chemistry
Physical Sciences
Preparations and properties
Science & Technology
LACTONES
ORGANIC-SYNTHESIS
ALDEHYDES
Five membered ring
Acetylenic compound
Hydroxylation
Trans stereoisomer
Carbon dioxide
Asymmetric reaction
Lactone
Oxygen heterocycle
Hydrometalation
Enynic compound
Successive reaction
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Summary:Optically active furfuryl alcohols and hydroxy butenolides are prepared from trans-1-trimethylsilyl-3-alken-1-ynes by the successive asymmetric dihydroxylation and hydromagnesiation reactions. Graphic
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(00)74061-5