Free ion yields in photoinduced electron transfer reactions from transient photoconductivity measurements: an overview

The transient photoconductivity (TP) technique for the determination of free ion yields in bimolecular photoinduced electron transfer reactions is critically discussed. Variation of experimental parameters such as the number of charge carriers, the applied electric field, the electrode spacing, and...

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Bibliographic Details
Published inJournal of photochemistry and photobiology. A, Chemistry. Vol. 121; no. 2; pp. 75 - 82
Main Authors von Raumer, Markus, Sarbach, Alexandre, Haselbach, Edwin
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 26.02.1999
Elsevier Science
Subjects
Chemistry
Exact sciences and technology
Free ion yields
General and physical chemistry
Photochemistry
Photoinduced electron transfer reactions
Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
Transient photoconductivity
Transient photoconductivity
Free ion yields
Photoinduced electron transfer reactions
Solvent effect
Reaction intermediate
Free ion
Bimolecular reaction
Temperature effect
Electron transfer
Review
Photochemical reaction
Electric field effect
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Summary:The transient photoconductivity (TP) technique for the determination of free ion yields in bimolecular photoinduced electron transfer reactions is critically discussed. Variation of experimental parameters such as the number of charge carriers, the applied electric field, the electrode spacing, and the viscosity of the solvent confirm the theoretical predictions.
ISSN:1010-6030
1873-2666
DOI:10.1016/S1010-6030(98)00454-7