Covalent chlorine incorporation during aniline polymerisation

Polyaniline formed electrochemically at high HCl concentration shows changes in its electrochemical properties which could be caused by covalent chlorine bonding to the polymer backbone. The bonding could be concluded from the analysis of the films infrared spectra.

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Bibliographic Details
Published inSynthetic metals Vol. 101; no. 1-3; p. 687
Main Authors Morales, G.M., Miras, M.C., Barbero, C.
Format Journal Article Conference Proceeding
LanguageEnglish
Published Lausanne Elsevier B.V 01.05.1999
Amsterdam Elsevier Science
New York, NY
Subjects
Applied sciences
Coupling reactions
Electrochemical polymerisation
Exact sciences and technology
Physicochemistry of polymers
Polyaniline and its derivatives
Polymerization
Polymers and radiations
Electrochemical polymerisation
Polyaniline and its derivatives
Coupling reactions
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Summary:Polyaniline formed electrochemically at high HCl concentration shows changes in its electrochemical properties which could be caused by covalent chlorine bonding to the polymer backbone. The bonding could be concluded from the analysis of the films infrared spectra.
ISSN:0379-6779
1879-3290
DOI:10.1016/S0379-6779(98)00765-6