Adsorption in semi-differential voltammetry

The function for the time semi-derivative of the reversible current response of a thin layer of adsorbed electroactive species in linear scan voltammetry is derived. Its properties are compared with the original current response, its semi-integral, and integral. This series is compared with the anal...

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Bibliographic Details
Published inJournal of electroanalytical chemistry (Lausanne, Switzerland) Vol. 455; no. 1; pp. 253 - 257
Main Author KLICKA, R
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 15.09.1998
Elsevier Science
Subjects
Adsorption
Chemistry
Convolution
Electrochemistry
Exact sciences and technology
General and physical chemistry
Semi-differentiation
Semi-integration
Study of interfaces
Thin layer
Voltammetry
Voltammetry
Semi-differentiation
Convolution
Thin layer
Semi-integration
Adsorption
Electrodes
Cyclic voltammetry
Integration
Theoretical study
Differentiation
Thin film
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Summary:The function for the time semi-derivative of the reversible current response of a thin layer of adsorbed electroactive species in linear scan voltammetry is derived. Its properties are compared with the original current response, its semi-integral, and integral. This series is compared with the analogous series of reversible semi-infinite linear diffusion current response and its differintegrations.
ISSN:1572-6657
1873-2569
DOI:10.1016/S0022-0728(98)00131-4