CONVENIENT SYNTHESIS OF ISOPRENOID CHLORIDES BY A DIRECT CHLORINATION PROCESS

A direct and easy chlorination of substituted isoprenoid derivatives in a hydrocarbon solvent affords allylic chlorides via an ene-type reaction. These mild conditions tolerate various functional groups and this procedure is very convenient for an industrial process.

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Bibliographic Details
Published inTetrahedron letters Vol. 33; no. 4; pp. 495 - 498
Main Authors MIGNANI, G, GRASS, JP, CHABARDES, P, MOREL, D
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier 1992
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
OLEFINS
COMPLEXES
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Summary:A direct and easy chlorination of substituted isoprenoid derivatives in a hydrocarbon solvent affords allylic chlorides via an ene-type reaction. These mild conditions tolerate various functional groups and this procedure is very convenient for an industrial process.
ISSN:0040-4039
DOI:10.1016/S0040-4039(00)93978-9