Mono-condensed product of ferrocenylformyl acetone with ethylenediamine and its complexes of lanthanide chlorides

A mono-condensed product (Fcen) ▪ was obtained from the condensation of ferrocenylformyl acetone with ethylenediamine and five new Fcen complexes of lanthanide chlorides having the formula Fcen 3LnC1 3 (where Ln = La, Nd, Gd, Dy and Lu) were synthesized via the reaction of Fcen with lanthanides. The...

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Bibliographic Details
Published inPolyhedron Vol. 8; no. 20; pp. 2459 - 2462
Main Authors Hu, Peizhi, Zhang, Lun, Zhu, Xiaobing, Liu, Xiyan, Ji, Licai, Chen, Yilong
Format Journal Article
LanguageEnglish
Published Oxford Elsevier Ltd 1989
New York, NY Elsevier Science
Subjects
Chemistry
Exact sciences and technology
Organic chemistry
Organometalloidal and organometallic compounds
Preparations and properties
Transition metals derivatives
Iron Complexes
Conductivity
Tetranuclear complex
Transition metal Complexes
Moessbauer spectrum
Lanthanum Complexes
Iron Lanthanum Complexes
Metallocene
Iron Organic compounds
Heteronuclear complex
Ultraviolet spectrum
Ketimine
Chloro complex
Infrared spectrum
Lanthanide Complexes
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Summary:A mono-condensed product (Fcen) ▪ was obtained from the condensation of ferrocenylformyl acetone with ethylenediamine and five new Fcen complexes of lanthanide chlorides having the formula Fcen 3LnC1 3 (where Ln = La, Nd, Gd, Dy and Lu) were synthesized via the reaction of Fcen with lanthanides. These lanthanide complexes were characterized by microanalyses, IR, UV, Mössbauer spectra, molar conductivities and TG—DTA graphs. The 1H NMR and MS spectra of Fcen were also recorded. In these complexes each Fcen is tridentately coordinated to the lanthanide ions and three chlorine atoms are outer-sphere anions.
ISSN:0277-5387
DOI:10.1016/S0277-5387(89)80010-5