Direct detection of HO2 radicals in the vicinity of TiO2 photocatalytic surfaces using cw-CRDS

• Published in: Applied catalysis. B, Environmental Vol. 99; no. 3-4; pp. 413 - 419
• Main Authors: Bahrini, Chiheb, Parker, Alexander, Schoemaecker, Coralie, Fittschen, Christa
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Kidlington Elsevier B.V 09.09.2010; Elsevier
• Subjects: Catalysis; Chemistry; Exact sciences and technology; General and physical chemistry; HO2 radicals; Photocatalysis; Photochemistry; Physical chemistry of induced reactions (with radiations, particles and ultrasonics); Remote oxidation; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; HO2 radicals; Photocatalysis; Remote oxidation; Binary compound; Hydrogen peroxide; radicals; Inorganic free radical; Transition element compounds; Glass; HO; Fluorescence; Air; Quantum yield; Plate; Degradation; Heterogeneous catalysis; Cavity; Detection limit; Oxidation; Gas phase; Titanium oxide; Environmental protection
• ISSN: 0926-3373; 1873-3883
• DOI: 10.1016/j.apcatb.2010.06.040

[Display omitted] ▶ Direct detection of HO2 radicals in the gas phase above TiO2 surface. ▶ In situ sensing of the gas phase above surfaces by cw-CRDS. ▶ Quantitative detection of H2O2 by cw-CRDS. This work describes the first ever direct detection of HO2 radicals in the gas phase above photocatalytic surfaces. A glass plate covered with TiO2 has been illuminated in the presence of H2O2 by a 20W fluorescence lamp centred at 365nm. The activity of the photocatalytic material has been proven through direct, time resolved observation of the degradation of H2O2 by following its concentration by the very sensitive and selective technique of cw-Cavity Ring Down Spectroscopy (cw-CRDS). An absorption line of H2O2 at 6639.89cm−1 has been used, permitting a detection limit of [H2O2]min=1.3 and 3.6×1013cm−3 for 50 and 200Torr of synthetic air, respectively. A lower limit of the quantum yield for H2O2 degradation has been estimated to ϕmin=0.0024. Under the same conditions, the formation of HO2 radicals has been detected directly and selectively in the gas phase, using the same technique. HO2 radicals have been observed at up to 4cm above the surface and at total pressures of up to 230Torr.