Effect of conformation of cyclic sulfide ligands on the mode of complexation to silver salts

The cyclic trisulfide 1,3,5-trithiane has a flattened chair conformation. It forms with AgSO 3CF 3 a dimeric complex wherein each silver is tetracoordinated bearing three sulfides and one triflate ion as ligands. On the other hand 1,4-dithiane, which also has a chair conformation, forms an infinite...

Full description

Saved in:
Bibliographic Details
Published inInorganica Chimica Acta Vol. 207; no. 2; pp. 263 - 265
Main Authors Edema, Jilles J.H., Buter, Jan, van Bolhuis, Fre, Meetsma, Auke, Kellogg, Richard M., Kooijman, Huub, Spek, Anthony L.
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 15.05.1993
Elsevier Science
Subjects
Chemistry
Condensed matter: structure, mechanical and thermal properties
Coordination compounds
Exact sciences and technology
Inorganic chemistry and origins of life
Inorganic compounds
Metal complexes
Physics
Preparations and properties
Structure of solids and liquids; crystallography
Structure of specific crystalline solids
Sulfur heterocycle
Molecular structure
Silver Complexes
Complexes Mixed
Dinuclear complex
Organic ligand
Transition metal Complexes
Experimental study
X ray diffraction
Crystalline structure
Sulfonate
Online AccessGet full text

Cover

More Information
Summary:The cyclic trisulfide 1,3,5-trithiane has a flattened chair conformation. It forms with AgSO 3CF 3 a dimeric complex wherein each silver is tetracoordinated bearing three sulfides and one triflate ion as ligands. On the other hand 1,4-dithiane, which also has a chair conformation, forms an infinite polymer with AgO 2CCF 3 wherein each silver is coordinated to two different dithianes and two different CF 3CO 2 ligands.
ISSN:0020-1693
1873-3255
DOI:10.1016/S0020-1693(00)90720-5