Synthesis of methyl- and methoxy-substituted poly( p-phenylene vinylene) via a non-ionic precursor route

Stable methyl- and methoxy-substituted soluble precursor polymers ( 5a and 5b) were synthesised via a non-ionic precursor route. These precursor polymers possess a sulphoxy substituent on the ethylene segment which, can be eliminated by means of a simple thermal treatment in order to yield the conju...

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Bibliographic Details
Published inSynthetic metals Vol. 84; no. 1; pp. 399 - 400
Main Authors Van Der Borght, M., Gelan, J., Vanderzande, D.
Format Journal Article Conference Proceeding
LanguageEnglish
Published Lausanne Elsevier B.V 1997
Amsterdam Elsevier Science
New York, NY
Subjects
Applied sciences
electroluminescence
Exact sciences and technology
Organic polymers
photoluminescence
Physicochemistry of polymers
Poly(phenylene vinylene) and derivatives
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
Poly(phenylene vinylene) and derivatives
electroluminescence
photoluminescence
Conjugated polymer
Chemical modification
Phenylene derivative polymer
Solution polycondensation
Optical properties
Preparation
Photoluminescence
Sulfoxide
Phenylenevinylene derivative polymer
Thermal reaction
Experimental study
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Summary:Stable methyl- and methoxy-substituted soluble precursor polymers ( 5a and 5b) were synthesised via a non-ionic precursor route. These precursor polymers possess a sulphoxy substituent on the ethylene segment which, can be eliminated by means of a simple thermal treatment in order to yield the conjugated polymer. The synthesis of the monomers, the precursor and the conjugated polymers is discussed briefly together with the photoluminescence properties of the latter.
ISSN:0379-6779
1879-3290
DOI:10.1016/S0379-6779(97)80801-6