Dry regenerable CuO/γ-Al2O3 catalyst for simultaneous removal of SOx and NOx from flue gas

• Published in: Applied catalysis. B, Environmental Vol. 119-120; pp. 297 - 303
• Main Authors: Rahmaninejad, Fatemeh, Gavaskar, Vasudeo S., Abbasian, Javad
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 30.05.2012; Elsevier
• Subjects: Catalysis; Chemistry; Copper oxide; Exact sciences and technology; Flue gas; General and physical chemistry; High temperature; NOx; Regenerable; Simultaneous; SOx; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Regenerable; NOx; Flue gas; High temperature; Simultaneous; Copper oxide; SOx; Desulfurization; Binary compound; Particle; Chemical reduction; Oxidation; Adsorbent; Aluminium oxide; Nitrogen oxide; Fluidized bed reactor; Oxygen; Catalytic reaction; Transition element compounds; Ions; Water vapor; Conversion; Ammonia; Heterogeneous catalysis; Alumina; Catalyst; Environmental protection
• ISSN: 0926-3373; 1873-3883
• DOI: 10.1016/j.apcatb.2012.03.005

[Display omitted] ► Novel regenerable CuO/γ-Al2O3 sorbent/catalyst were evaluated for NOx removal from flue gas. ► The CuO/γ-Al2O3 catalyst was shown to be capable of removing close to 100% of NOx in both oxidized (regenerated), and sulfated state in fluidized bed reactor. ► The presence of steam was shown to enhance the catalytic activity. ► The catalytic activity of the sorbent/catalyst was shown to be unaffected by the cyclic process after 25 cycles. The catalytic activity of a highly reactive and attrition resistant regenerable CuO/γ-Al2O3 desulfurization sorbent for NOx reduction was determined in a fluidized-bed reactor. The NO conversion over the sulfated catalyst was found to be higher than that obtained over the fresh/oxidized catalyst, with the optimum temperatures for the maximum NO removal at 350°C for both catalysts. The decrease in NO conversion above the optimum temperature is attributed to the increase in the rate of the parallel NH3 oxidation reaction. High levels of ammonia oxidation (i.e., >96%) was observed in absence of oxygen and NO with oxidized sorbent/catalyst, indicating the participation of the lattice oxygen ions in the CuO/γ-Al2O3 particles in the NH3 oxidation reaction. The presence of steam enhances the catalytic activity of the catalysts providing a wider optimum temperature window, thus resulting in a more flexible operation for simultaneous SOx/NOx removal from flue gas.