Group 8 Transition Metal Complexes of the Tripodal Triphosphino Ligands PhSi(CH2PR2)3 (R = Ph, iPr)

• Published in: European journal of inorganic chemistry Vol. 2013; no. 36; pp. 6075 - 6078
• Main Authors: Neumeyer, Felix, Lipschutz, Michael I., Tilley, T. Don
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 09.12.2013; WILEY‐VCH Verlag; Wiley Subscription Services, Inc
• Subjects: Iron; Ligands; NMR; Nuclear magnetic resonance; Osmium; Phosphane; Ruth­enium; Tridentate ligands

A series of group 8 transition metal complexes of new tridentate phosphine ligands with Fe, Ru, and Os were prepared. The new complexes were characterized by multinuclear NMR spectroscopy and X‐ray crystallography. Complexes of iron, ruthenium, and osmium with the neutral tridentate tripodal phosphi...