Group 8 Transition Metal Complexes of the Tripodal Triphosphino Ligands PhSi(CH2PR2)3 (R = Ph, iPr)

A series of group 8 transition metal complexes of new tridentate phosphine ligands with Fe, Ru, and Os were prepared. The new complexes were characterized by multinuclear NMR spectroscopy and X‐ray crystallography. Complexes of iron, ruthenium, and osmium with the neutral tridentate tripodal phosphi...

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Published inEuropean journal of inorganic chemistry Vol. 2013; no. 36; pp. 6075 - 6078
Main Authors Neumeyer, Felix, Lipschutz, Michael I., Tilley, T. Don
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 09.12.2013
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
Iron
Ligands
NMR
Nuclear magnetic resonance
Osmium
Phosphane
Ruth­enium
Tridentate ligands
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Summary:A series of group 8 transition metal complexes of new tridentate phosphine ligands with Fe, Ru, and Os were prepared. The new complexes were characterized by multinuclear NMR spectroscopy and X‐ray crystallography. Complexes of iron, ruthenium, and osmium with the neutral tridentate tripodal phosphine ligands PhSi(CH2PPh2)3 and PhSi(CH2PiPr2)3 show tetrahedral coordination for iron and form cationic dimeric octahedral complexes with the heavier homologues ruthenium and osmium.
Bibliography:istex:E4C8E6DBEB2A0A065B777FB727809F02AB898100
ArticleID:EJIC201301074
ark:/67375/WNG-8MXQ4X01-N
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.201301074