Synthesis and characterization of novel h-HTBN/PEG PU copolymers for tissue engineering: degradation, phase behavior, and mechanical properties
The phase behavior of the as‐prepared polyether polyurethane (PU) elastomers was investigated by dynamic mechanical analysis (DMA), polarized optical microscope (POM), and atomic force microscopy (AFM). This PU copolymers were composed of different compositions of two soft segments, poly(ethylene gl...
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Published in | Polymers for advanced technologies Vol. 22; no. 11; pp. 1478 - 1486 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Chichester, UK
John Wiley & Sons, Ltd
01.11.2011
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Subjects | |
Online Access | Get full text |
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Summary: | The phase behavior of the as‐prepared polyether polyurethane (PU) elastomers was investigated by dynamic mechanical analysis (DMA), polarized optical microscope (POM), and atomic force microscopy (AFM). This PU copolymers were composed of different compositions of two soft segments, poly(ethylene glycol) (PEG) and hydrolytically modified hydroxyl‐terminated poly(butadiene‐co‐acrylonitrile) (h‐HTBN) oligomers. The microphase separation behavior is confirmed to occur between soft and hard segments as well as soft and soft segments as the h‐HTBN is incorporated into the PU system, depending on soft‐soft and/or soft‐hard microdomain composition, molecular weight (MW) of PEG, and hydrolysis time of HTBN. The driving force for this phase separation is mainly due to the formation of inter‐ and intramolecular hydrogen bonding interaction. The PU‐70, PU‐50 samples with non‐reciprocal composition seem to exhibit larger microphase separation than any other PU ones. The hydrolysis degradation, thermal stability, and mechanical properties of the copolymers were assessed by gravimetry, scanning electron microscope (SEM), thermal gravity analysis (TGA), and tensile test, respectively. The experimental results indicated that the incorporation of h‐HTBN soft segment into PEG as well as low MW of PEG leads to increased thermal and degradable stability based on the intermolecular hydrogen bond interaction. The PU‐70 and PU‐50 copolymers exhibit better mechanical properties such as high flexibility and high ductility because of their larger microphase separation architecture with the hard domains acting as reinforcing fillers and/or physical crosslinking agents dispersed in the soft segment matrix. Copyright © 2009 John Wiley & Sons, Ltd. |
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Bibliography: | ark:/67375/WNG-4PKTMD0L-D National Natural Science Foundation of China - No. 10675078 istex:400273EEE51DE632B64F3AF5CB7E1BF868FAE286 ArticleID:PAT1631 ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
ISSN: | 1042-7147 1099-1581 1099-1581 |
DOI: | 10.1002/pat.1631 |