Recent applications of radical cascade reaction in the synthesis of functionalized 1-indenones

[Display omitted] 1-Indenones are important scaffolds in natural products, biologically active molecules as well as functional materials. Recently, radical cascade cyclization has emerged as an efficient and powerful strategy for the construction of valuable and versatile functionalized 1-indenones....

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Bibliographic Details
Published inChinese chemical letters Vol. 30; no. 7; pp. 1361 - 1368
Main Authors Zhang, Yinli, Sun, Kai, Lv, Qiyan, Chen, Xiaolan, Qu, Lingbo, Yu, Bing
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.07.2019
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China%College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China
Henan Nonferrous Metals Geological Exploration Institute, Zhengzhou 450052, China
Subjects
1,3-Diarylpropynones
1-Indenones
2-Alkynylbenzonitriles
Arylpropynols
Radical cascade reaction
Arylpropynols
Radical cascade reaction
1,3-Diarylpropynones
2-Alkynylbenzonitriles
1-Indenones
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Summary:[Display omitted] 1-Indenones are important scaffolds in natural products, biologically active molecules as well as functional materials. Recently, radical cascade cyclization has emerged as an efficient and powerful strategy for the construction of valuable and versatile functionalized 1-indenones. In this review, the recent advances of this rapidly growing area were summarized. The selected examples have been classified according to the type of reaction substrates such as 1,3-diarylpropynones, 2-alkynylbenzonitriles, arylpropynols, 1,5-enynes and 2-alkynylated bromocinnamates.
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2019.03.034