Synthesis and Characterization of Some Thallium Cyclopentadienide Fused Ring Pyridazines

Thallium cyclopentadiene (Cp) salts are important precursors for the synthesis of a variety of compounds having materials and commercial applications. The synthesis of 5,6-fused ring thallium Cp pyridazines 2a-d from previously reported 5,6-fused ring pyridazines is described herein. This route was...

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Bibliographic Details
Published inSynthetic communications Vol. 43; no. 18; pp. 2441 - 2451
Main Authors Young, Jason O. E., Snyder, Chad A., Tice, Nathan C., Sloan, Seth L., Smith, Adam C., Shah, Sana A., Dopierala, Levi A., Crocker, Michael S., Kobayashi, Yuto, Mazzotta, Michael G.
Format Journal Article
LanguageEnglish
Published PHILADELPHIA Taylor & Francis Group 17.09.2013
Taylor & Francis
Taylor & Francis Ltd
Subjects
1,2-diacylcyclopentadiene
Chemistry
Chemistry, Organic
Cyclopentadiene
fulvenes
Physical Sciences
pyridazines
Science & Technology
thallium
1
Cyclopentadiene
pyridazines
COMPLEXES
fulvenes
2-diacylcyclopentadiene
thallium
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Summary:Thallium cyclopentadiene (Cp) salts are important precursors for the synthesis of a variety of compounds having materials and commercial applications. The synthesis of 5,6-fused ring thallium Cp pyridazines 2a-d from previously reported 5,6-fused ring pyridazines is described herein. This route was quite general, and features an efficient and convenient two-step synthesis of a series of TlCp salts in a THF solution of thallium ethoxide. Full characterization of newly formed TlCp salts 3a-d are reported.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397911.2012.698356