S-(3-Chloro-2-oxo-propyl)-O-ethyl xanthate: a linchpin radical coupling agent for the synthesis of heterocyclic and polycyclic compounds

The preparation and use of S-(3-chloro-2-oxo-propyl)-O-ethyl xanthate to directly introduce an a-chloroketone motif is described, along with applications for the synthesis of heterocyclic and polycyclic structures.

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Bibliographic Details
Published inOrganic & biomolecular chemistry Vol. 4; no. 2; pp. 278 - 290
Main Authors Bergeot, O, Corsi, C, El Qacemi, M, Zard, SZ
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 21.01.2006
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
(-)-PERHYDROHISTRIONICOTOXIN
CONVENIENT
THIAZOLE
ASYMMETRIC-SYNTHESIS
FORMAL SYNTHESIS
DOLASTATIN-3
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Summary:The preparation and use of S-(3-chloro-2-oxo-propyl)-O-ethyl xanthate to directly introduce an a-chloroketone motif is described, along with applications for the synthesis of heterocyclic and polycyclic structures.
ISSN:1477-0520
1477-0539
DOI:10.1039/b514509k