The remarkable crystal structure of the dimeric species [bis( ortho-anisyl)magnesium · THF] 2

The crystal structure of dimeric bis( ortho-methoxyphenyl)magnesium tetrahydrofuranate, 1, has been determined, and found to be remarkably unsymmetrical. The magnesium atoms in 1 have different coordination numbers and are connected by two ortho-methoxyphenyl groups each bridging in a unique fashion...

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Published inJournal of organometallic chemistry Vol. 411; no. 3; pp. 291 - 302
Main Authors Markies, Peter R., Schat, Gerrit, Villena, Alan, Akkerman, Otto S., Bickelhaupt, F., Smeets, Wilbert J.J., Spek, Anthony L.
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 09.07.1991
Elsevier Science
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Summary:The crystal structure of dimeric bis( ortho-methoxyphenyl)magnesium tetrahydrofuranate, 1, has been determined, and found to be remarkably unsymmetrical. The magnesium atoms in 1 have different coordination numbers and are connected by two ortho-methoxyphenyl groups each bridging in a unique fashion.
ISSN:0022-328X
1872-8561
DOI:10.1016/0022-328X(91)83036-4