Highly selective anodic monofluorination of 4-arylthio-1,3-dioxolan-2-ones: a marked solvent effect on product selectivity

This is the first example of a solvent effect on fluorinated product selectivity; anodic fluorination of 4-arylthio-1,3-dioxolan-2-ones in CH2Cl2 containing a fluoride supporting electrolyte using an undivided cell provided the fluorodesulfurization product, 4-fluoro-1,3-dioxolan-2-one preferentiall...

Full description

Saved in:
Bibliographic Details
Published inChemical communications (Cambridge, England) no. 17; pp. 1617 - 1618
Main Authors Ishii, H, Yamada, N, Fuchigami, T
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2000
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
MONO-FLUORINATION
ELECTROLYTIC PARTIAL FLUORINATION
ORGANIC-COMPOUNDS
DIFLUORINATION
Online AccessGet full text

Cover

More Information
Summary:This is the first example of a solvent effect on fluorinated product selectivity; anodic fluorination of 4-arylthio-1,3-dioxolan-2-ones in CH2Cl2 containing a fluoride supporting electrolyte using an undivided cell provided the fluorodesulfurization product, 4-fluoro-1,3-dioxolan-2-one preferentially while anodic fluorination in DME resulted in alpha-fluorination, without desulfurization, selectively.
ISSN:1359-7345
1364-548X
DOI:10.1039/b004652n