Regio- and stereo-selective synthesis of multi-substituted 3-pyrrolines

A regio- and stereo-selective synthesis of multi-substituted 3-pyrrolines has been developed. The multi-substituted 3-pyrrolines were synthesized in good yields by 1,3-dipolar cycloaddition of methyl 2-(phenylselanyl)acrylate with azomethine ylides, followed by N-acylation and oxidation–elimination...

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Bibliographic Details
Published inChinese chemical letters Vol. 20; no. 9; pp. 1015 - 1016
Main Authors Xu, Jian Feng, Li, Peng Bin, Wu, Lu Ling, Huang, Xian
Format Journal Article
LanguageEnglish
Published NEW YORK Elsevier B.V 01.09.2009
Elsevier
State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China
Department of Chemistry,Zhejiang University(Campus Xixi),Hangzhou 310028,China%Department of Chemistry,Zhejiang University(Campus Xixi),Hangzhou 310028,China
Subjects
1,3-Dipolar cycloaddition
3-Pyrrolines
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Regioselective
Science & Technology
Stereoselective
1,3-Dipolar cycloaddition
Regioselective
3-Pyrrolines
Stereoselective
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Summary:A regio- and stereo-selective synthesis of multi-substituted 3-pyrrolines has been developed. The multi-substituted 3-pyrrolines were synthesized in good yields by 1,3-dipolar cycloaddition of methyl 2-(phenylselanyl)acrylate with azomethine ylides, followed by N-acylation and oxidation–elimination of phenylseleno group.
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2009.04.037