Synthesis and characterization of 2,6-bis(imino)phenoxy cobalt complexes

A series of cobalt complexes bearing 2,6-bis (imino) phenoxy ligands, LCoCl2 [L = 2,6-(ArNCH)(2)CH3C6H2OH] was synthesized by the reaction of the ligand 2,6-bis(imino) phenol with the equivalent mole of cobalt dichloride, and these complexes were characterized by elemental analyses, H-1 NMR, MS and...

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Bibliographic Details
Published inChinese journal of chemistry Vol. 20; no. 12; pp. 1523 - 1528
Main Authors Han, LQ, Sun, WH, Wang, LY, Shao, CX, Wang, HG, Li, JT
Format Journal Article
LanguageEnglish
Published WEINHEIM Wiley 01.12.2002
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
crystal structure
Schiff-base
POLYMERIZATION
ETHYLENE
cobalt complex
CATALYSTS
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Summary:A series of cobalt complexes bearing 2,6-bis (imino) phenoxy ligands, LCoCl2 [L = 2,6-(ArNCH)(2)CH3C6H2OH] was synthesized by the reaction of the ligand 2,6-bis(imino) phenol with the equivalent mole of cobalt dichloride, and these complexes were characterized by elemental analyses, H-1 NMR, MS and ER spectra. The structure of one complex was determined by single crystal X-ray diffraction analysis.
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.20020201212