Coordinated and Clathrated Molecular Diiodine in [Rh2(O2CCF3)4I2]⋅I2

A bidentate bridging coordination of molecular diiodine has been found for the first time in [Rh2(O2CCF3)4I2]⋅I2, which was obtained by deposition from the vapor phase. An X‐ray structure reveals a zigzag chain polymer (shown in the picture) formed by alternating [Rh2(O2CCF3)4] and I2 molecules; ano...

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Published inAngewandte Chemie (International ed.) Vol. 39; no. 13; pp. 2362 - 2364
Main Authors Cotton, F. Albert, Dikarev, Evgeny V., Petrukhina, Marina A.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH 03.07.2000
WILEY‐VCH Verlag GmbH
Subjects
carboxylato complexes
clathrates
coordination modes
iodine
rhodium
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Summary:A bidentate bridging coordination of molecular diiodine has been found for the first time in [Rh2(O2CCF3)4I2]⋅I2, which was obtained by deposition from the vapor phase. An X‐ray structure reveals a zigzag chain polymer (shown in the picture) formed by alternating [Rh2(O2CCF3)4] and I2 molecules; another diiodine molecule is clathrated within the channels of the network.
Bibliography:istex:CD24D88A1DD14A38CCC9EE5898374FB9541DBD4D
ArticleID:ANIE2362
ark:/67375/WNG-7VVG5KKC-W
Studies of Dirhodium
II
Tetrakis(trifluoroacetate), part 7. This work was supported by the Robert A. Welch Foundation. Part 6: ref. 2c.
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20000703)39:13<2362::AID-ANIE2362>3.0.CO;2-V