Development and performance characteristics of silane crosslinked poly(vinyl alcohol)/chitosan membranes for reverse osmosis

• Published in: Journal of industrial and engineering chemistry (Seoul, Korea) Vol. 48; pp. 99 - 107
• Main Authors: Shafiq, M., Sabir, A., Islam, A., Khan, S.M., Hussain, S.N., Z. Butt, M.T.Z., Jamil, T.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 25.04.2017; 한국공업화학회
• Subjects: Chitosan; Desalination; Membrane; Permeation; Reverse osmosis; 화학공학; Membrane; Reverse osmosis; Chitosan; Desalination; Permeation
• ISSN: 1226-086X; 1876-794X
• DOI: 10.1016/j.jiec.2016.12.025

[Display omitted] •Silane crosslinked PVA/CS membranes were fabricated by dissolution casting.•Thermal, morphological and RO properties of membranes were studied.•Crosslinked PVA/CS membranes showed greater hydrophilic performance.•The antibacterial properties showed the inhibition of growth of Escherichia coli.•Salt rejection rate (>80%) was improved due to TEOS loading. Novel thin film poly(vinyl alcohol)/chitosan (PVA/CS) based reverse osmosis membranes infused with silane crosslinked tetraethylorthosilicate (TEOS) were prepared by dissolution casting methodology. The performance characteristics and the scope of the reverse osmosis membranes were explicated by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analyzer (TGA), differential scanning calorimetery (DSC), scanning electron microscopy (SEM), contact angle, X-ray diffraction (XRD) and reverse osmosis (RO) permeation tests which determined the functional groups and network of covalent crosslinks, thermal properties, morphology, hydrophilicity, structural investigation and RO properties, respectively. It was found that the membrane surface became smoother, more hydrophilic, with improved thermal stability, increased salt rejection and good permeation flux after the appropriate infusion of TEOS. The crosslinked membranes showed more hydrophilicity compared to the uncrosslinked PVCS membrane. The SEM micrographs of membranes revealed dense structure with no mottled surfaces. PVCS-4 showed an optimal flux of 1.84L/m2h and 80% salt rejection that confirmed the selective interaction of TEOS molecules with PVA/CS polymer backbone compared to the pristine (PVCS) membrane. The antibacterial properties of the membranes showed the inhibition of the growth of Escherichia coli successfully.