The Molecular Design of "Carcass"-Type Phosphoranes, Based on the Reaction of P(III)-Cyclic Derivatives and Unsaturated Activated Compounds

The methodology for the synthesis of carcass-type (cage-like type) phosphoranes was developed, which allows us to obtain the products of the given structure with a high regio- and stereoselectivity in the result of cascade processes.

Saved in:
Bibliographic Details
Published inPhosphorus, sulfur, and silicon and the related elements Vol. 186; no. 4; pp. 652 - 656
Main Authors Abdrakhmanova, L. M., Мironov, V. F., Gryaznova, T. P., Katsyuba, S. A., Dimukhametov, M. N.
Format Journal Article
LanguageEnglish
Published Abingdon Taylor & Francis Group 31.03.2011
Taylor & Francis Ltd
Subjects
Cascade reaction
chloral
hexafluoroacetone
phosphonate
phosphorane
quantum-chemical calculations
X-ray analysis
Online AccessGet full text

Cover

More Information
Summary:The methodology for the synthesis of carcass-type (cage-like type) phosphoranes was developed, which allows us to obtain the products of the given structure with a high regio- and stereoselectivity in the result of cascade processes.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426507.2010.521434