Direct oxidative amidation between methylarenes and amines in water

An environmentally friendly direct oxidative amidation between methylarenes and free amines was developed. The aromatic amide could be prepared efficiently from raw chemicals by employing TBHP as a "green" oxidant with co-catalysis of TBAI and FeCl3 in water.

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Bibliographic Details
Published inGreen chemistry : an international journal and green chemistry resource : GC Vol. 17; no. 5; pp. 2741 - 2744
Main Authors Wang, Tao, Yuan, Lin, Zhao, Zhenguang, Shao, Ailong, Gao, Meng, Huang, Yangfei, Xiong, Fei, Zhang, Huali, Zhao, Junfeng
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.05.2015
Subjects
Amides
Amines
Chemistry
Chemistry, Multidisciplinary
Green & Sustainable Science & Technology
Oxidants
Oxidizing agents
Physical Sciences
Raw
Science & Technology
Science & Technology - Other Topics
AROYLATION
CATALYSIS
PEPTIDES
AMIDE SYNTHESIS
ESTERIFICATION
LIGATION
BOND FORMATION
ALDEHYDES
C-H ACTIVATION
PRIMARY ALCOHOLS
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Summary:An environmentally friendly direct oxidative amidation between methylarenes and free amines was developed. The aromatic amide could be prepared efficiently from raw chemicals by employing TBHP as a "green" oxidant with co-catalysis of TBAI and FeCl3 in water.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1463-9262
1463-9270
DOI:10.1039/c5gc00299k