Assessment of the application of cladode cactus mucilage flocculants for hot chemical degreasing electroplating wastewater treatment and reuse: process efficiency and storage stability

• Published in: Water science and technology Vol. 86; no. 5; pp. 938 - 949
• Main Authors: Riahi, Khalifa, Chaabane, Safa, Werhenin Ammeri, Rim, Jaballah, Adel, Dörr, Michael
• Format: Journal Article
• Language: English
• Published: London IWA Publishing 01.09.2022
• Subjects: Acids; Alkalinity; Bacteria; Biodegradation; Biopolymers; Chemical oxygen demand; Cleaning process; Climate change; Coagulation; Correspondence; Corrosion; Corrosion potential; Degreasing; Electroplating; Flocculants; Flocculation; Growth; Industrial areas; Industrial wastewater; Jar tests; Mesophilic bacteria; Microorganisms; Mucilage; Mucilages; Off odor; Oxidation; Oxidation-reduction potential; Pathogens; Photosystem I; Plating; Redox potential; Scale (corrosion); Scaling; Storage stability; Sustainable development; Sustainable use; Urban sprawl; Variance analysis; Wastewater treatment; Water resources; Water treatment; Yeasts; Zinc; Tunisia
• ISSN: 0273-1223; 1996-9732
• DOI: 10.2166/wst.2022.261

Abstract Pressures related to urban growth and industrial activities exacerbated by climate change had an impact on water resources in Tunisia. The present study examines the application of cladode cactus mucilage (CCM) flocculants for hot alkaline chemical degreasing Zn-electroplating wastewater treatment and reuse (WWTR). The CCM flocculation process was selected through their environmental benefits, economic facilities, sustainable use of the natural biopolymer product, input biopolymers substitution, and on-site treated wastewater (TWW) reuse and recovery. The alum coagulation and CCM flocculation were performed by the jar test series. The suitability of treated wastewater quality (TWWQ) with alum/CCM was also assessed for reuse purpose in terms of corrosion-scaling indices (RSI, LSI, PSI, AI), oxidation-reduction potential (ORP), and microbiological community growth (Bacillus, Pseudomonas, Mesophilic bacteria and yeasts) for 28 days storage at 25 °C. The total alkalinity removal efficiency reached 95.8% with an optimum dosage of alum + CCM for hot alkaline chemical degreasing wastewater bath rinsing. The results showed that the stability of TWWQ has significantly deteriorated during storage leading to aggressive wastewater, pathogen growth, and biological malodor production which make them unsuitable for reuse. Therefore, there is a need for CCM processing alternatives that preserve the physico-chemical and microbial of TWW properties during storage.