Synthesis, characterization, and properties of petroleum-based methacrylate polymers derived from tricyclodecane for microelectronics and optoelectronics applications

[Display omitted] Three types of petroleum-based tricycloalkyl-containing methacrylate polymers derived from adamantane and DCPD were synthesized and characterized, poly(1-adamantyl methacrylate) (PADMA), poly(tricyclodecyl methacrylate) (PTCDMA) and poly(1-adamantyl methacrylate-co-tricyclodecyl me...

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Published inJournal of industrial and engineering chemistry (Seoul, Korea) Vol. 53; pp. 143 - 154
Main Authors Tsai, Chih-Wei, Wu, Kuo-Hui, Wang, Je-Chuang, Shih, Chien-Chou
Format Journal Article
LanguageEnglish
Published Elsevier B.V 25.09.2017
한국공업화학회
Subjects
Adamantane
Optoelectronic properties
PMMA
Thermo-mechanical properties
Tricyclodecane
화학공학
Adamantane
Tricyclodecane
PMMA
Optoelectronic properties
Thermo-mechanical properties
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Summary:[Display omitted] Three types of petroleum-based tricycloalkyl-containing methacrylate polymers derived from adamantane and DCPD were synthesized and characterized, poly(1-adamantyl methacrylate) (PADMA), poly(tricyclodecyl methacrylate) (PTCDMA) and poly(1-adamantyl methacrylate-co-tricyclodecyl methacrylate) (P(ADMA-co-TCDMA)). As expected, the incorporation of a tricycloalkyl substituent as a pendant group on the methacrylate polymer contributed to enhancement of thermal stability in combination with high transparency in the UV–vis region and long-term thermal resistance, in addition to improved mechanical properties, a lower CTE, decreased water absorption and a lower dielectric constant. These merits make tricycloalkyl-containing methacrylate polymers promising candidates for use as high value-added optical plastics in the microelectronics and optoelectronics applications.
ISSN:1226-086X
1876-794X
DOI:10.1016/j.jiec.2017.04.019