Comparison of dried sludge and sludge ash for phosphorus recovery with acidic and alkaline leaching

• Published in: Water and environment journal : WEJ Vol. 35; no. 1; pp. 359 - 370
• Main Authors: Semerci, Neslihan, Ahadi, Saifurahman, Coşgun, Sevil
• Format: Journal Article
• Language: English
• Published: London Wiley Subscription Services, Inc 01.02.2021
• Subjects: Alkaline leaching; Ambient temperature; Ashes; chemical leaching; dried sludge; Food security; Food sources; Heavy metals; Leachates; Leaching; Metal concentrations; Metals; Phosphorus; phosphorus recovery; phosphorus release; Recovery; Sewage; Sewage sludge; Sludge; sludge ash; Sodium hydroxide; Temperature
• ISSN: 1747-6585; 1747-6593
• DOI: 10.1111/wej.12633

Nowadays, the recovery of phosphorus has been in the spotlight due to its importance for food security and depleting sources. In this study, phosphorus recovery from dried sewage sludge and sludge ash by acid and alkaline leaching was evaluated. Optimum extraction time and temperature were determined as two hours and ambient temperature. Results showed the superiority of strong acidic conditions for leaching; 75 ml/g with 0.4N HCl and 25 ml/g with 0.6N HCl were determined as optimum conditions to achieve efficient phosphorus dissolution from sludge ash (94.6%) and dried sludge (91.1%), respectively, with the lower heavy metal concentrations. Lower L/S ratio put forward the dried sludge as a more advantageous resource for phosphorus extraction. Besides, by alkaline leaching of sludge ash and dried sludge, 60.3 and 70.3% phosphorus dissolutions were achieved with 75 ml/g and 1N NaOH; and the leachate was a suitable product for phosphorus precipitation due to its high pH.