Identification of disaccharides by gas chromatography-Fourier transform infrared spectroscopy
The use of GC-Fourier transform (FT) IR of methylsilyl ethers of disaccharides to positively identify disaccharides is reported for the first time. The conditions required to separate these high-molecular-mass compounds by GC, in the quantities required for FT-IR detection are reported. Trimethylsil...
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Published in | Journal of Chromatography A Vol. 750; no. 1; pp. 311 - 316 |
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Main Authors | , |
Format | Journal Article Conference Proceeding |
Language | English |
Published |
Amsterdam
Elsevier B.V
25.10.1996
Elsevier |
Subjects | |
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Abstract | The use of GC-Fourier transform (FT) IR of methylsilyl ethers of disaccharides to positively identify disaccharides is reported for the first time. The conditions required to separate these high-molecular-mass compounds by GC, in the quantities required for FT-IR detection are reported. Trimethylsilyl ethers can be used successfully. The use of dimethylsilyl ethers is not recommended as their instability, under the required operating conditions, resulted in fragmentation and rearrangements. |
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AbstractList | The use of GC-Fourier transform (FT) IR of methylsilyl ethers of disaccharides to positively identify disaccharides is reported for the first time. The conditions required to separate these high-molecular-mass compounds by GC, in the quantities required for FT-IR detection are reported. Trimethylsilyl ethers can be used successfully. The use of dimethylsilyl ethers is not recommended as their instability, under the required operating conditions, resulted in fragmentation and rearrangements. |
Author | Veness, R.G. Evans, C.S. |
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Cites_doi | 10.1016/0021-9673(95)00767-9 10.1021/ja00899a032 |
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Keywords | Disaccharides Carbohydrates Derivatization, GC Infrared spectrometry Gas chromatography Fourier transformation Chemical analysis Coupled method Silylation Qualitative analysis Glycoside Derivatization Disaccharide |
Language | English |
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References | Chaplin (BIB2) 1987 Foulkes, Brooks (BIB5) 1984 Bell, Lott (BIB9) 1962 Bartel (BIB6) 1993 Veness, Evans (BIB4) 1996; 721 Wells, Sweeley, Bentley (BIB7) 1964 R.G. Veness, unpublished results. Dejong (BIB1) 1980; Vol. 1B Bellamy (BIB3) 1962 Sweeley, Bentley, Makita, Wells (BIB8) 1963; 85 Bartel (10.1016/0021-9673(96)00281-6_BIB6) 1993 Chaplin (10.1016/0021-9673(96)00281-6_BIB2) 1987 Bellamy (10.1016/0021-9673(96)00281-6_BIB3) 1962 Veness (10.1016/0021-9673(96)00281-6_BIB4) 1996; 721 Bell (10.1016/0021-9673(96)00281-6_BIB9) 1962 Dejong (10.1016/0021-9673(96)00281-6_BIB1) 1980; Vol. 1B Wells (10.1016/0021-9673(96)00281-6_BIB7) 1964 Sweeley (10.1016/0021-9673(96)00281-6_BIB8) 1963; 85 10.1016/0021-9673(96)00281-6_BIB10 Foulkes (10.1016/0021-9673(96)00281-6_BIB5) 1984 |
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SubjectTerms | Analytical chemistry Carbohydrates Chemistry Chromatographic methods and physical methods associated with chromatography Derivatization, GC Disaccharides Exact sciences and technology Gas chromatographic methods |
Title | Identification of disaccharides by gas chromatography-Fourier transform infrared spectroscopy |
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