Kinetic modelling of the retention of nitrates by Amberlite IRA 410
The rate of retention of nitrates on a synthetic resin, Amberlite IRA 410, was measured at 22°C. Three simplified kinetic models, pseudo-first-order, pseudo-second-order and intraparticle diffusion were tested in order to determine the mechanisms during the nitrates uptake. The influence of paramete...
Saved in:
Published in | Desalination Vol. 185; no. 1; pp. 509 - 515 |
---|---|
Main Authors | , |
Format | Journal Article Conference Proceeding |
Language | English |
Published |
Amsterdam
Elsevier B.V
01.11.2005
Elsevier |
Subjects | |
Online Access | Get full text |
Cover
Loading…
Summary: | The rate of retention of nitrates on a synthetic resin, Amberlite IRA 410, was measured at 22°C. Three simplified kinetic models, pseudo-first-order, pseudo-second-order and intraparticle diffusion were tested in order to determine the mechanisms during the nitrates uptake. The influence of parameters such as the stirring velocity, the size of the particles, the mass of the resin and the concentration of the solution was examined.
The results were shown that the fixing of nitrates could be best described by the pseudo second order and the intraparticle diffusion models. The coefficients of correlation obtained during the adjustment of the experimental values to the two models are higher than 98% what gives access to the kinetic parameters of the two models. The dependence of kinetics parameters on initial concentration and mass adsorbent is represented by the simple empirical equations. The normalized standard deviations between the simulated and measured results were calculated and discussed. |
---|---|
ISSN: | 0011-9164 1873-4464 |
DOI: | 10.1016/j.desal.2005.04.054 |