Conversions of [2-(4,5-dihydrofuryl)]-silanes and -germanes under catalytic hydrogenation conditions

(2-Tetrahydrofuryl)-silanes and -germanes were obtained in high yield by the heterogeneous liquid-phase hydrogenation of [2-(4,5-dihydrofuryl)]trimethylsilane (I), bis[2-(4,5-dihydrofuryl)]dimethylsilane (II) and [2-(4,5-dihydrofuryl)]trimethylgermane with a Pd/Al 2O 3 catalyst. The dihydrofurylsila...

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Bibliographic Details
Published inJournal of organometallic chemistry Vol. 294; no. 2; pp. 163 - 171
Main Authors Lukevics, E., Gevorgyan, V.N., Goldberg, Y.S., Shymanska, M.V.
Format Journal Article
LanguageEnglish
Published LAUSANNE 1 Elsevier B.V 01.01.1985
Elsevier
Elsevier Science
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Exact sciences and technology
Organic chemistry
Organometalloidal and organometallic compounds
Physical Sciences
Preparations and properties
Science & Technology
Si derivatives
Germanium Organic compounds
Five membered ring
Silicon Organic compounds
Mass spectrum
Palladium
Oxygen heterocycle
NMR spectrum
Hydrogenation
Supported catalyst
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Summary:(2-Tetrahydrofuryl)-silanes and -germanes were obtained in high yield by the heterogeneous liquid-phase hydrogenation of [2-(4,5-dihydrofuryl)]trimethylsilane (I), bis[2-(4,5-dihydrofuryl)]dimethylsilane (II) and [2-(4,5-dihydrofuryl)]trimethylgermane with a Pd/Al 2O 3 catalyst. The dihydrofurylsilanes I and II were found to undergo disproportionation and dehydrogenation, the latter being involved in both intra- and inter-molecular disproportionation.
ISSN:0022-328X
1872-8561
DOI:10.1016/0022-328X(85)87465-9