Chemiluminescence of protected hemiaminal N-methoxymethyl-N′-methyl-9,9′-biacridylidene in homogeneous and micellar media. Prospects for analytical applications

The light reaction of protected hemiaminal 3 ( N-methoxymethyl-′-methyl-9,9′-biacridylidene) with singlet oxygen and alkaline hydrogen peroxide in homogeneous and micellar media is reported. The chemiluminescence and fluorescence quantum yields and light intensities in those media are also reported....

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Bibliographic Details
Published inAnalytica chimica acta Vol. 304; no. 1; pp. 91 - 96
Main Authors Papadopoulos, K., Nikokavouras, J., Mitsoulis, K., Dimotikali, D.
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 20.03.1995
Elsevier
Subjects
Chemiluminescence
Chemistry
Exact sciences and technology
General and physical chemistry
Micelles
N-Methoxymethyl-N′-methyl-9,9′-biacridylidene
N-Methoxymethyl-N′-methyl-9,9′-biacridylidene
Micelles
Chemiluminescence
Nitrogen heterocycle
Acridine derivatives
Fluorescence
Surfactant
Derivatization
Experimental study
Quantum yield
Hydrogen Peroxides
Medium effect
Hemiaminal
Micellar solution
Organic compounds
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Summary:The light reaction of protected hemiaminal 3 ( N-methoxymethyl-′-methyl-9,9′-biacridylidene) with singlet oxygen and alkaline hydrogen peroxide in homogeneous and micellar media is reported. The chemiluminescence and fluorescence quantum yields and light intensities in those media are also reported. Hemiaminal 3 is suitable for competition reactions in the presence of organic reductants for analytical applications.
ISSN:0003-2670
1873-4324
DOI:10.1016/0003-2670(94)00546-X