The study of the composition and catalytic properties of palladium(II) complexes with poly(VINYLPYRIDINE)

The composition and catalytic properties of palladium(II) complexes supported on poly(vinylpyridine) in the hydrogenation of unsaturated aldehydes and alcohols in water and ethanol are discussed. The catalytic activity has been shown to depend on the composition of the complexes and the valency stat...

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Published inJournal of molecular catalysis Vol. 55; no. 1; pp. 406 - 414
Main Authors Zharmagambetova, A.K., Golodov, V.A., Saltykov, Yu.P.
Format Journal Article Conference Proceeding
LanguageEnglish
Published Lausanne Elsevier B.V 01.11.1989
Elsevier Sequoia
Subjects
Chemistry
Exact sciences and technology
General and physical chemistry
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Summary:The composition and catalytic properties of palladium(II) complexes supported on poly(vinylpyridine) in the hydrogenation of unsaturated aldehydes and alcohols in water and ethanol are discussed. The catalytic activity has been shown to depend on the composition of the complexes and the valency state of the palladium contained therein. The reaction rate is also determined by the ability of the complexes to swell in organic solvents and by the diffusion of reactants to active centres within the bulk of the polymer-metal complexes.
ISSN:0304-5102
DOI:10.1016/0304-5102(89)80275-5