Bidentate P,N ligand-modified rhodium(I) complexes: the impact of nitrogen ligands on isomerization capability

Chlororhodium(I) complexes containing cyclic aminophosphonites PhP ▪NR (R = H, Me) catalyze the hydrogenation of 1-hexene. Isomerization is an important side reaction and is explained by the formation of hydridorhodium(l) species which result from the ▪NR induced HCl abstraction from rhodium(III) di...

Full description

Saved in:
Bibliographic Details
Published inJournal of organometallic chemistry Vol. 279; no. 1; pp. C1 - C4
Main Authors Bonnet, M.C., Stitou, B., Tkatchenko, I.
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 01.01.1985
Elsevier Science
Subjects
Catalysis
Catalysts: preparations and properties
Catalytic reactions
Chemistry
Exact sciences and technology
General and physical chemistry
General. Nomenclature, chemical documentation, computer chemistry
Theory of reactions, general kinetics
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Olefin
Isomerization
Rhodium I Complexes
Catalyst
Online AccessGet full text

Cover

More Information
Summary:Chlororhodium(I) complexes containing cyclic aminophosphonites PhP ▪NR (R = H, Me) catalyze the hydrogenation of 1-hexene. Isomerization is an important side reaction and is explained by the formation of hydridorhodium(l) species which result from the ▪NR induced HCl abstraction from rhodium(III) dihydrides.
ISSN:0022-328X
1872-8561
DOI:10.1016/0022-328X(85)87027-3