Nitration of catecholamines with nitrogen oxides in mild conditions: a hypothesis for the reactivity of NO in physiological systems
Dopamine, norepinephrine and epinephrine react at room temperature, in acetate buffer (36) with sodium nitrite or in non-deaerated phosphate buffer (pH 7.4) with NO. The corresponding 6-nitro derivatives are formed. Catecholamines react at pH 3–6 with sodium nitrite or in non-deaerated buffer (pH 7....
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| Published in | Tetrahedron letters Vol. 35; no. 39; pp. 7231 - 7232 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
OXFORD
Elsevier Ltd
26.09.1994
Elsevier |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Dopamine, norepinephrine and epinephrine react at room temperature, in acetate buffer (36) with sodium nitrite or in non-deaerated phosphate buffer (pH 7.4) with NO. The corresponding 6-nitro derivatives are formed.
Catecholamines react at pH 3–6 with sodium nitrite or in non-deaerated buffer (pH 7.4) with NO leading to the 6-nitro derivatives. |
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| AbstractList | Dopamine, norepinephrine and epinephrine react at room temperature, in acetate buffer (36) with sodium nitrite or in non-deaerated phosphate buffer (pH 7.4) with NO. The corresponding 6-nitro derivatives are formed.
Catecholamines react at pH 3–6 with sodium nitrite or in non-deaerated buffer (pH 7.4) with NO leading to the 6-nitro derivatives. Dopamine, norepinephrine and epinephrine react at room temperature, in acetate buffer (3<pH<6) with sodium nitrite or in non-deaerated phosphate buffer (pH 7.4) with NO. The corresponding 6-nitro derivatives are formed. |
| Author | Lenfant, Maryse Servy, Claudine Ducrocq, Claire de la Bretèche, Marie-Laure |
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| Cites_doi | 10.1056/NEJM199302113280605 10.1039/p29940000335 10.1080/00397918608057689 10.1016/0014-5793(93)81748-O 10.1016/S0040-4020(01)82044-5 10.1039/p29850000467 10.1016/0278-6915(90)90173-K 10.1038/327524a0 10.1039/C39930001377 10.1016/0040-4020(89)80046-8 10.1016/0014-2999(93)90352-I 10.1021/tx00031a003 |
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| Keywords | NITRIC-OXIDE 2-PHASE NITRATION PHENOLS KINETICS Nitration Dopamine Nitrogen monoxide Benzenic compound Buffer solution Diphenols Aminophenols Sodium Nitrites |
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| SubjectTerms | Chemistry Chemistry, Organic Exact sciences and technology Noncondensed benzenic compounds Organic chemistry Physical Sciences Preparations and properties Science & Technology |
| Title | Nitration of catecholamines with nitrogen oxides in mild conditions: a hypothesis for the reactivity of NO in physiological systems |
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