Rapid assembly of highly-functionalised difluorinated cyclooctenones via ring-closing metathesis

Building block methodology from trifluoroethanol and ring-closing metathesis using a Furstner modification of Grubbs' conditions allows the rapid synthesis of novel difluorinated cyclooctenones.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 3; pp. 228 - 229
Main Authors Kariuki, BM, Owton, WM, Percy, JM, Pintat, S, Smith, CA, Spencer, NS, Thomas, AC, Watson, M
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 07.02.2002
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
REARRANGEMENTS
ONE-POT SYNTHESIS
TRIFLUOROMETHYLTRIMETHYLSILANE
ORGANOFLUORINE-ORGANOSILICON CHEMISTRY
GLUCOSE
ACYLSILANES
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Summary:Building block methodology from trifluoroethanol and ring-closing metathesis using a Furstner modification of Grubbs' conditions allows the rapid synthesis of novel difluorinated cyclooctenones.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1359-7345
1364-548X
DOI:10.1039/b109651f