Improvements in Methyl-Bambus[6]uril Synthesis Yield

Bambus[n]uril synthesis may be challenging, and it is frequently achieved with low purity and low yields. We have studied the effect of different anions on the synthesis of bambus[6]uril, especially in terms of yield, exploring template effects driven by anions in the reaction medium. The influence...

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Bibliographic Details
Published inJournal of the Brazilian Chemical Society Vol. 31; no. 11; pp. 2232 - 2236
Main Authors de Carvalho, Julio, Cicolani, Renato, Demets, Grégoire
Format Journal Article
LanguageEnglish
Published Sociedade Brasileira de Química 01.11.2020
Subjects
CHEMISTRY, MULTIDISCIPLINARY
caviplexes
anion-template
bambusuril
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Summary:Bambus[n]uril synthesis may be challenging, and it is frequently achieved with low purity and low yields. We have studied the effect of different anions on the synthesis of bambus[6]uril, especially in terms of yield, exploring template effects driven by anions in the reaction medium. The influence of the anions is evident on such syntheses and ClO4− particularly led to unprecedented synthesis yields. Computational calculations have also been used to elucidate the influence of anions on cyclization process.
ISSN:0103-5053
1678-4790
DOI:10.21577/0103-5053.20200074