Molecular Main Group Metal Hydrides

This review serves to document advances in the synthesis, versatile bonding, and reactivity of molecular main group metal hydrides within Groups 1, 2, and 12-16. Particular attention will be given to the emerging use of said hydrides in the rapidly expanding field of Main Group element-mediated cata...

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Bibliographic Details
Published inChemical reviews Vol. 121; no. 20; pp. 12784 - 12965
Main Authors Roy, Matthew M D, Omaña, Alvaro A, Wilson, Andrew S S, Hill, Michael S, Aldridge, Simon, Rivard, Eric
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 27.10.2021
Subjects
Catalysis
Chemical synthesis
Metal hydrides
Metals
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Summary:This review serves to document advances in the synthesis, versatile bonding, and reactivity of molecular main group metal hydrides within Groups 1, 2, and 12-16. Particular attention will be given to the emerging use of said hydrides in the rapidly expanding field of Main Group element-mediated catalysis. While this review is comprehensive in nature, focus will be given to research appearing in the open literature since 2001.
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ISSN:0009-2665
1520-6890
DOI:10.1021/acs.chemrev.1c00278