Effect of Cu/Co ratio in CuaCo1−aOx (a = 0.1, 0.2, 0.4, 0.6) flower structure on its surface properties and catalytic performance for toluene oxidation

• Published in: Journal of colloid and interface science Vol. 599; pp. 404 - 415
• Main Authors: Fan, Liman, Li, Mingyang, Zhang, Cheng, Ismail, Ahmed, Hu, Boren, Zhu, Yujun
• Format: Journal Article
• Language: English
• Published: Elsevier Inc 01.10.2021
• Subjects: Improved oxidation capability; Mixed Cu-Co oxides; Surface adsorbed oxygen; Toluene oxidation; Surface adsorbed oxygen; Toluene oxidation; Improved oxidation capability; Mixed Cu-Co oxides
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/j.jcis.2021.04.058

The oxidation of toluene to H2O and CO2 is more rapidly over the Cu0.4Co0.6Ox catalyst than Co3O4 due to the more surface adsorbed oxygen, more Co3+ cationic species derived from the strong interaction between Cu and Co oxidation (Co2+ + Cu2+ ↔ Co3+ + Cu+). [Display omitted] •Cu0.4Co0.6Ox with dumbbell-shaped flowers structure for catalytic toluene oxidation.•Good activity of Cu0.4Co0.6Ox due to increasing surface Co3+ and adsorbed oxygen.•Strong interaction between Cu and Co oxides enhanced toluene conversion. Catalytic oxidation is considered a high-efficient method to minimize efficiently toluene emission. It is still a challenge to improve the catalytic performance for toluene oxidation by modifying the surface properties to enhance the oxidation ability of catalyst. Herein, a series of CuaCo1−aOx (a = 0.1, 0.2, 0.4, 0.6) catalysts were synthesized via solvothermal method and applied for toluene oxidation. The effects of the Cu/Co ratio on the texture structure, morphology, redox property and surface properties were investigated by various characterization technologies. The Cu0.4Co0.6Ox catalyst with dumbbell-shaped flower structure exhibited much lower temperature of 50% and 100% toluene conversion and far higher reaction rate (13.96 × 10−2 μmol·g−1·s−1) at 220 °C than the Co based oxides in previous reports. It is found that the good activity can be attributed to the fact that the proper Cu/Co ratio can significantly improve the formation of more surface adsorbed oxygen and Co3+ species, leading to the much higher oxidation ability came from the strong interaction between Cu and Co oxides. It is suggested that toluene should be oxidized more rapidly to CO2 and H2O over the Cu0.4Co0.6Ox catalyst than Co3O4 based on the results of in situ DRIFTS.