Synthesis and Molecular Structure of 2-(4-Chlorophenyl)-3-(phenyl-amino)-5-(thiophen-2-ylmethylidene)-3,5-dihydro-4H-imidazol-4-one

2-(4-Chlorophenyl)-3-(phenylamino)-5-(thiophen-2-ylmethylidene)-3,5-dihydro-4 H -imidazol-4-one, C 20 H 14 N 3 OSCl was synthesized and its crystal structure was determined by single crystal X-ray diffraction. The crystals are triclinic, sp. gr. P 1, Z = 2. All three rings are planar, and imidazole...

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Bibliographic Details
Published inCrystallography reports Vol. 62; no. 7; pp. 1148 - 1151
Main Authors Sharma, Devinder K., Subbulakshmi, K. N., Narayana, B., Sarojini, B. K., Anthal, Sumati, Kant, R.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.12.2017
Springer Nature B.V
Subjects
Chemical bonds
Chemical synthesis
CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
CRYSTAL STRUCTURE
Crystallography and Scattering Methods
Dihedral angle
DIMERS
HYDROGEN
Hydrogen bonds
Imidazole
IMIDAZOLES
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
MOLECULAR STRUCTURE
MOLECULES
MONOCRYSTALS
Physics
Physics and Astronomy
RINGS
Single crystals
Structure of Organic Compounds
SYNTHESIS
X-RAY DIFFRACTION
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Summary:2-(4-Chlorophenyl)-3-(phenylamino)-5-(thiophen-2-ylmethylidene)-3,5-dihydro-4 H -imidazol-4-one, C 20 H 14 N 3 OSCl was synthesized and its crystal structure was determined by single crystal X-ray diffraction. The crystals are triclinic, sp. gr. P 1, Z = 2. All three rings are planar, and imidazole ring is almost perpendicular to the phenyl ring with the dihedral angle of 88.65(2)°. In the crystal, pairs of O–H···O hydrogen bonds link molecules into inversion dimers, featuring R 22 (10) graph set motif. Crystal structure is further stabilized by π···π interactions.
ISSN:1063-7745
1562-689X
DOI:10.1134/S1063774517070082