A stereoselective synthesis of (±)-homogynolide-B

A highly stereoselective formal total synthesis of homogynolide-B via the ketoketals 4 and the ketospirolactone 3a starting from Hagemann's ester 2 is described. Graphic

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Bibliographic Details
Published inTetrahedron letters Vol. 35; no. 3; pp. 429 - 432
Main Authors Srikrishna, Adusumilli, Nagaraju, Sankuratri, Venkateswarlu, Somepalli
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 17.01.1994
Elsevier
Subjects
Alicyclic compounds, terpenoids, prostaglandins, steroids
Chemistry
Chemistry, Organic
Exact sciences and technology
Organic chemistry
Physical Sciences
Preparations and properties
Science & Technology
Terpenoids
ALPINA
BAKKANES
Stereoselectivity
Five membered ring
Sesquiterpenes
Bicyclic compound
Racemate
Lactone
Ketoester
Oxygen heterocycle
Ketone
Enone
Monocyclic compound
Spiran
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Summary:A highly stereoselective formal total synthesis of homogynolide-B via the ketoketals 4 and the ketospirolactone 3a starting from Hagemann's ester 2 is described. Graphic
ISSN:0040-4039
1873-3581
DOI:10.1016/0040-4039(94)85072-0