NOVEL HEAD-TO-TAIL ALKYL-ALKENE OR ALKENE-ALKENE COUPLING VIA ZIRCONIUM-CATALYZED REACTION OF ALKYLMAGNESIUM DERIVATIVES WITH MONOSUBSTITUTED ALKENES
The reaction of monosubstituted alkenes with alkylmagnesium derivatives catalyzed by Cp2ZrCl2 or related zirconocene derivatives provides head-to-tail alkyl-alkene or alkene-alkene coupling products, approximately 50% of which are 2,5-dialkyl-4-pentenylmagnesium halides.
Saved in:
Published in | Tetrahedron letters Vol. 33; no. 15; pp. 1965 - 1968 |
---|---|
Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
OXFORD
Elsevier
07.04.1992
|
Subjects | |
Online Access | Get more information |
Cover
Loading…
Summary: | The reaction of monosubstituted alkenes with alkylmagnesium derivatives catalyzed by Cp2ZrCl2 or related zirconocene derivatives provides head-to-tail alkyl-alkene or alkene-alkene coupling products, approximately 50% of which are 2,5-dialkyl-4-pentenylmagnesium halides. |
---|---|
ISSN: | 0040-4039 |
DOI: | 10.1016/0040-4039(92)88115-L |